Stereospecific generation of homochiral helices in coordination polymers built from enantiopure binaphthyl-based ligands

Author:

Crespo Alonso M.1234,Arca M.1234,Isaia F.1234,Lai R.1234,Lippolis V.1234,Callear S. K.567,Caricato M.8910,Pasini D.8910ORCID,Coles S. J.1112131415ORCID,Aragoni M. C.1234

Affiliation:

1. Dipartimento di Scienze Chimiche e Geologiche

2. Università degli Studi di Cagliari

3. Cittadella Universitaria

4. 09042 Monserrato Cagliari, Italy

5. ISIS Facility

6. Rutherford Appleton Laboratory

7. Didcot, UK

8. Department of Chemistry and INSTM Research Unit

9. University of Pavia

10. 27100 Pavia, Italy

11. UK National Crystallography Service

12. Chemistry

13. Faculty of Natural and Environmental Sciences

14. University of Southampton

15. Southampton, UK

Abstract

The novel enantiopure spacer 2,2′-dimethoxy-1,1′-binaphthyl-3,3′-bis(4-pyridyl-amido) has been designed to prepare helical coordination polymers here investigated by means of experimental and theoretical data.

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

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