First example of solid-state luminescent borasiloxane-based chiral helices assembled through N

First example of solid-state luminescent borasiloxane-based chiral helices assembled through N–B bonds

Published:2021 Issue:11 Volume:50 Page:3782-3785
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Podda Enrico¹²³⁴⁵,Coles Simon J.⁶⁷⁸⁹¹⁰^ORCID,Horton Peter N.⁶⁷⁸⁹¹⁰,Lickiss Paul D.¹¹¹²¹³¹⁰^ORCID,Bull Okpara S.¹¹¹²¹³¹⁰,Orton James B.⁶⁷⁸⁹¹⁰,Pintus Anna¹²³⁴⁵,Pugh David¹⁴¹⁵¹⁰^ORCID,Carla Aragoni M.¹²³⁴⁵^ORCID,Davies Robert P.¹¹¹²¹³¹⁰^ORCID

Affiliation:

1. Dipartimento di Scienze Chimiche e Geologiche

2. Università Degli Studi di Cagliari

3. Cittadella Universitaria

4. Monserrato-Cagliari

5. Italy

6. National Crystallography Service

7. School of Chemistry

8. University of Southampton

9. Southampton

10. UK

11. Molecular Sciences Research Hub

12. Imperial College London

13. White City

14. Department of Chemistry

15. London

Abstract

The reaction between differently substituted borasiloxanes and 2,5-bis(3-pyridylethynyl)thiophene provided the first example of luminescent borasiloxane-based chiral helices held together by N–B bonds.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/DT/D1DT00114K

Reference33 articles.

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4. Trisiloxane-centred metal–organic frameworks and hydrogen bonded assemblies

5. Studies on the structural diversity of MOFs containing octahedral siloxane-backboned connectors

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