Artificial co-enzyme based on carbamoyl-modified viologen derivative cation radical for formate dehydrogenase in the catalytic CO2 reduction to formate
Author:
Affiliation:
1. School of Materials and Chemical Technology
2. Tokyo Institute of Technology
3. Yokohama 226-8502
4. Japan
5. Graduate School of Science
6. Osaka City University
7. Osaka 558-8585
8. Research Centre of Artificial Photosynthesis (ReCAP)
Abstract
The interaction between the single-electron reduced carbamoyl-modified-4,4-bipyridinium salt and CbFDH in the CO2 reduction to formate is elucidated by enzymatic kinetic analysis, the docking simulation and density functional theory calculation.
Publisher
Royal Society of Chemistry (RSC)
Subject
Materials Chemistry,General Chemistry,Catalysis
Link
http://pubs.rsc.org/en/content/articlepdf/2020/NJ/D0NJ04375C
Reference70 articles.
1. Smart CO 2 Transformation (SCOT) project in EU Seventh Framework Program, http://scotproject.org
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5. Synthesis, Structure, and Catalysis of Palladium Complexes Bearing a Group 13 Metalloligand: Remarkable Effect of an Aluminum-Metalloligand in Hydrosilylation of CO2
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