Multipole-moment effects in ion–molecule reactions at low temperatures: part I – ion-dipole enhancement of the rate coefficients of the He+ + NH3 and He+ + ND3 reactions at collisional energies Ecoll/kB near 0 K

Author:

Zhelyazkova Valentina1ORCID,Martins Fernanda B. V.1ORCID,Agner Josef A.1,Schmutz Hansjürg1,Merkt Frédéric1ORCID

Affiliation:

1. ETH Zurich, Zurich, Switzerland

Abstract

The energy dependence of the rates of the reactions between He+ and ammonia (NY3, Y = {H,D}), forming NY2+, Y and He as well as NY+, Y2 and He has been measured at low collision energies near 0 K.

Funder

H2020 European Research Council

Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Reference81 articles.

1. Gas Phase Ion Chemistry: Vol. 1 and 2 , ed. M. T. Bowers , Academic Press , New York , 1979

2. Kinetics of Ion-Molecule Reactions , ed. P. Ausloos , Plenum Press , New York , 1978

3. Calculations of rate constants for ion-molecule reactions using a combined capture and centrifugal sudden approximation

4. Fast Chemical Reactions: Theory Challenges Experiment

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