Solution size variation of linear and dendritic bis-MPA analogs using DOSY-1H NMR-Reference-Cited by-同舟云学术

Solution size variation of linear and dendritic bis-MPA analogs using DOSY-1H NMR

Published:2021 Issue:10 Volume:12 Page:1507-1517
ISSN:1759-9954
Container-title:Polymer Chemistry
language:en
Short-container-title:Polym. Chem.

Author:

Kareem Oluwapelumi O.¹²³⁴⁵,Rahmani Farzin⁶⁷⁸⁹⁵,Hyman Jason A.¹²³⁴⁵,Keller Christopher B.¹²³⁴⁵,Pasquinelli Melissa A.⁶⁷⁸⁹⁵^ORCID,Savin Daniel A.¹¹⁰¹¹¹²⁵^ORCID,Grayson Scott M.¹²³⁴⁵^ORCID

Affiliation:

1. Department of Chemistry

2. Percival Stern Hall

3. Tulane University

4. New Orleans

5. USA

6. Department of Forest Biomaterials

7. Biltmore Hall

8. North Carolina State University

9. Raleigh

10. Leigh Hall

11. University of Florida

12. Gainesville

Abstract

The size and size variability of bis-MPA dendrimers is shown to be smaller by DOSY-¹H NMR than their linear analog, PBBM. This was accomplished using five different solvents and for the first time confirms, experimentally, what has been theorized.

Funder

Southern Regional Education Board

Louisiana Board of Regents

Division of Chemistry

American Chemical Society Petroleum Research Fund

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

Link

http://pubs.rsc.org/en/content/articlepdf/2021/PY/D0PY01070G

Reference38 articles.

1. About Dendrimers: Structure, Physical Properties, and Applications

2. Chemistry of multifunctional polymers based on bis-MPA and their cutting-edge applications

3. Advances in the chemistry of dendrimers

4. Dendronized Supramolecular Nanocapsules: pH Independent, Water-Soluble, Deep-Cavity Cavitands Assemble via the Hydrophobic Effect

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