Understanding the high reactivity of carbonyl compounds towards nucleophilic carbenoid intermediates generated from carbene isocyanides-Reference-Cited by-同舟云学术

Understanding the high reactivity of carbonyl compounds towards nucleophilic carbenoid intermediates generated from carbene isocyanides

Published:2015 Issue:103 Volume:5 Page:84797-84809
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Ríos-Gutiérrez Mar¹²³⁴⁵,Domingo Luis R.¹²³⁴⁵,Pérez Patricia⁶⁷⁸⁹¹⁰

Affiliation:

1. Universidad de Valencia

2. Facultad de Química

3. Departamento de Química Orgánica

4. E-46100 Burjassot

5. Spain

6. Universidad Andrés Bello

7. Facultad de Ciencias Exactas

8. Departamento de Ciencias Químicas

9. Santiago

10. Chile

Abstract

The high nucleophilic character of the carbenoid intermediate cis-IN together with the specific approach mode of acetone make the formation of the C–C single bond with a very low activation free energy, possible.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/RA/C5RA15662A

Reference107 articles.

1. Recent Developments in Isocyanide Based Multicomponent Reactions in Applied Chemistry

2. Polymerization of isocyanides

3. Multicomponent Reactions with Isocyanides

4. Isocyanoacetate Derivatives: Synthesis, Reactivity, and Application

5. Recent application of isocyanides in synthesis of heterocycles

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