Effect of ligand substituents on nickel and copper [N4] complexes: electronic and redox behavior, and reactivity towards protons-Reference-Cited by-同舟云学术

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Effect of ligand substituents on nickel and copper [N4] complexes: electronic and redox behavior, and reactivity towards protons

Published:2019 Issue:32 Volume:43 Page:12795-12803
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Kankanamalage Pavithra H. A.¹²³⁴,Ekanayake Danushka M.¹²³⁴,Singh Nirupama¹⁵⁶⁴,de Morais Ana C. P.⁷⁸⁹¹⁰^ORCID,Mazumder Shivnath¹¹¹¹²¹³^ORCID,Verani Cláudio N.¹²³⁴^ORCID,Mukherjee Anusree¹⁵⁶⁴^ORCID,Lanznaster Mauricio⁷⁸⁹¹⁰^ORCID

Affiliation:

1. Department of Chemistry

2. Wayne State University

3. Detroit

4. USA

5. University of Alabama

6. Huntsville

7. Instituto de Química

8. Universidade Federal Fluminense

9. Niterói

10. Brazil

11. Indian Institute of Technology Jammu

12. Jammu (J&K)

13. India

Abstract

The ligand substituents have a major effect on the redox potentials, catalytic efficiency and robustness of the complexes in HER.

Funder

Conselho Nacional de Desenvolvimento Científico e Tecnológico

University of Alabama in Huntsville

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior

Basic Energy Sciences

Wayne State University

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2019/NJ/C9NJ01283D

Reference57 articles.

1. Electrocatalytic Hydrogen Evolution in Acidic Water with Molecular Cobalt Tetraazamacrocycles

2. A tridentate Ni pincer for aqueous electrocatalytic hydrogen production

3. Highly efficient molecular nickel catalysts for electrochemical hydrogen production from neutral water

4. Molecular Cobalt Pentapyridine Catalysts for Generating Hydrogen from Water

5. An approach to water-soluble hydrogenase active site models: Synthesis and electrochemistry of diiron dithiolate complexes with 3,7-diacetyl-1,3,7-triaza-5-phosphabicyclo[3.3.1]nonane ligand(s)

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