Exploring the Potential of Water-Soluble Cu(II) Complexes with MPA–CdTe Quantum Dots for Photoinduced Electron Transfer

Abstract

Three water-soluble copper complexes based on the amine/pyridine functionalities were investigated, along with quantum dots, as a catalyst–photosensitizer assembly, respectively, for fundamental understanding of photoinduced electron transfer. Luminescence quenching and lifetime measurements were performed to try and establish the actual process that leads to the quenching, such as electron transfer, energy transfer, or complex formation (static quenching). Cyclic voltammetry and dynamic light scattering experiments were also performed. Irrespective of the similar reduction potentials of the three complexes, very different photoluminescence properties were observed.