Core-modified 48π and 42π decaphyrins: syntheses, properties and structures-Reference-Cited by-同舟云学术

Core-modified 48π and 42π decaphyrins: syntheses, properties and structures

Published:2019 Issue:22 Volume:6 Page:3746-3753
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Ghosh Arindam¹²³⁴^ORCID,Dash Syamasrit¹²³⁴^ORCID,Srinivasan A.¹²³⁴^ORCID,Suresh C. H.⁵⁶⁷⁸⁴^ORCID,Peruncheralathan S.¹²³⁴^ORCID,Chandrashekar Tavarekere K.¹²³⁴^ORCID

Affiliation:

1. School of Chemical Sciences

2. National Institute of Science Education and Research (NISER)

3. Bhubaneswar-752050

4. India

5. Inorganic and Theoretical Chemistry section

6. Chemical Science and Technology Division

7. CSIR-National Institute of Interdisciplinary Science and Technology

8. Trivandrum – 695019

Abstract

Protonation triggered transition of a 48π nonaromatic decaphyrin to a 48π Hückel antiaromatic decaphyrin is reported: the flexibility of the macrocycle due to the presence of twelve meso carbon bridges facilitates such a transition through conformational change.

Funder

National Institute of Science Education and Research

Department of Atomic Energy, Government of India

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/QO/C9QO01162E

Reference68 articles.

1. Expanded Porphyrins: Intriguing Structures, Electronic Properties, and Reactivities

2. Synthetic Expanded Porphyrin Chemistry