Synthesis of a novel twisted π-conjugated macrocycle via double Friedel–Crafts reaction and its physical properties

Author:

Jiang Zhiyan1ORCID,Kuninobu Yoichiro21ORCID

Affiliation:

1. Department of Interdisciplinary Engineering Sciences, Interdisciplinary Graduate School of Engineering Sciences, Kyushu University, 6-1 Kasugakoen, Kasuga-Shi, Fukuoka 816-8580, Japan

2. Institute for Materials Chemistry and Engineering, Kyushu University, 6-1 Kasugakoen, Kasuga-Shi, Fukuoka 816-8580, Japan

Abstract

We report the synthesis of a novel twisted π-conjugated macrocycle bridged by C(sp3) atoms by double Friedel–Crafts reaction. This molecule is a rare example of a π-conjugated macrocyclic system with homoconjugation.

Funder

Japan Science and Technology Corporation

Japan Society for the Promotion of Science

Tokuyama Science Foundation

Publisher

Royal Society of Chemistry (RSC)

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