Molecular-scale study of Cr(<scp>vi</scp>) adsorption onto lepidocrocite facets by EXAFS, <i>in situ</i> ATR-FTIR, theoretical frequency calculations and DFT+U techniques-Reference-Cited by-同舟云学术

Molecular-scale study of Cr(vi) adsorption onto lepidocrocite facets by EXAFS, in situ ATR-FTIR, theoretical frequency calculations and DFT+U techniques

Published:2022 Issue:2 Volume:9 Page:568-581
ISSN:2051-8153
Container-title:Environmental Science: Nano
language:en
Short-container-title:Environ. Sci.: Nano

Author:

Li Xiaofei¹,Guo Chuling¹²,Jin Xiaohu¹,Yao Qian¹,Liu Qianqian¹,Zhang Lijuan³,Lu Guining¹²,Reinfelder John R.⁴,Huang Weilin⁴,Dang Zhi¹²^ORCID

Affiliation:

1. School of Environment and Energy, South China University of Technology, Guangzhou 510006, PR China

2. The Key Lab of Pollution Control and Ecosystem Restoration in Industry Clusters, Ministry of Education, South China University of Technology, Guangzhou 510006, PR China

3. School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510006, PR China

4. Department of Environmental Sciences, Rutgers University, New Brunswick, NJ 08901, USA

Abstract

Lepidocrocite, as a ubiquitous iron mineral, is widely detected in different morphologies in natural environments, controlling the mobility and availability of heavy metal ions (HMIs).

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

General Environmental Science,Materials Science (miscellaneous)

Link

http://pubs.rsc.org/en/content/articlepdf/2022/EN/D1EN01085A

Reference52 articles.

1. Size-Driven Structural and Thermodynamic Complexity in Iron Oxides

2. Mechanisms of Cr(VI) adsorption on schwertmannite under environmental disturbance: Changes in surface complex structures

3. Investigation of Chromate Coordination on Ferrihydrite by in Situ ATR-FTIR Spectroscopy and Theoretical Frequency Calculations