Accessing libraries of bifunctional block copolymers using two distinct pentafluorophenyl moieties-Reference-Cited by-同舟云学术

Accessing libraries of bifunctional block copolymers using two distinct pentafluorophenyl moieties

Published:2016 Issue:48 Volume:7 Page:7488-7499
ISSN:1759-9954
Container-title:Polymer Chemistry
language:en
Short-container-title:Polym. Chem.

Author:

Varadharajan Divya¹²³⁴⁵,Delaittre Guillaume¹²³⁴⁵

Affiliation:

1. Institute of Toxicology and Genetics

2. Karlsruhe Institute of Technology (KIT)

3. 76344 Eggenstein-Leopoldshafen

4. Germany

5. Preparative Macromolecular Chemistry

Abstract

The suitability of pentafluorophenyl (PFP) esters and PFP alkyl moieties for orthogonal dual functionalization of block copolymer segments is evaluated. While amidation followed by para-fluoro–thiol substitution is a viable reaction sequence, thiol-based substitution can occur on PFP esters at a high rate, thereby hampering the viability of the reverse sequence.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

Link

http://pubs.rsc.org/en/content/articlepdf/2016/PY/C6PY01711H

Reference30 articles.

1. Thiol-Ene Click Chemistry

2. Click Chemistry: Diverse Chemical Function from a Few Good Reactions

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4. “Clicking” Polymers or Just Efficient Linking: What Is the Difference?

5. Synthesis of pentafluorophenyl(meth)acrylate polymers: New precursor polymers for the synthesis of multifunctional materials

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