Unprecedented silicon(ii)→calcium complexes with N-heterocyclic silylenes-Reference-Cited by-同舟云学术

Unprecedented silicon(ii)→calcium complexes with N-heterocyclic silylenes

Published:2015 Issue:2 Volume:44 Page:639-644
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Blom Burgert¹²³⁴,Klatt Günter⁵⁶⁴,Gallego Daniel¹²³⁴,Tan Gengwen¹²³⁴,Driess Matthias¹²³⁴

Affiliation:

1. Technische Universität Berlin

2. Department of Chemistry: Metalorganics and Inorganic Materials

3. 10623 Berlin

4. Germany

5. Physikalisch-Chemisches Institut der Universität Heidelberg

6. D-69120 Heidelberg

Abstract

The first N-heterocyclic silylene (NHSi) complexes of any s-block element to date are reported for calcium: [(η⁵-C₅Me₅)₂Ca←:Si(O-C₆H₄-2-^tBu){(N^tBu)₂CPh}] and [(η⁵-C₅Me₅)₂Ca←:Si(N^tBuCH)₂]. The synthesis, structure, bonding analysis by DFT methods and the reactivity towards oxygen containing substrates is discussed.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C4DT03148B

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5. Evaluation of a Silylene Divalent Lanthanide Interaction in the Metallocene Complex (C5Me5)2Sm[SiNtBuCHCHNtBu]

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