[(Flu)-(CH2)2-(NHC)-CH2-(NHC)-(CH2)2-(Flu)]2−: an ‘all-organic’ hybrid and flexible ligand that enwraps a Ca2+ pseudo-tetrahedrally-Reference-Cited by-同舟云学术

[(Flu)-(CH₂)₂-(NHC)-CH₂-(NHC)-(CH₂)₂-(Flu)]²⁻: an ‘all-organic’ hybrid and flexible ligand that enwraps a Ca²⁺ pseudo-tetrahedrally

Published:2022 Issue:87 Volume:58 Page:12188-12191
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Baguli Sudip¹,Das Shovan²,Chakraborty Mahua¹,Goswami Santu¹,Datta Ayan²^ORCID,Mukherjee Debabrata¹^ORCID

Affiliation:

1. Department of Chemical Sciences, Indian Institute of Science Education and Research Kolkata, Mohanpur, Nadia, West Bengal 741246, India

2. School of Chemical Sciences, Indian Association for the Cultivation of Science, 2A and 2B Raja SC Mallick Road, Jadavpur, Kolkata, 700032, India

Abstract

A conformationally flexible ligand, [(Flu)-(CH2)2-(NHC)-CH2-(NHC)-(CH2)2-(Flu)]2− (L), that offers four sequential organic donor modules and enwraps a Ca2+ pseudo-tetrahedrally in a twisted ‘S’-shape is devised.

Funder

Science and Engineering Research Board

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CC/D2CC04700D

Reference64 articles.

1. Metal–organic frameworks based on flexible ligands (FL-MOFs): structures and applications

2. T.Storr , Ligand Design in Medicinal Inorganic Chemistry , Wiley , 2014

3. Use of Achiral and Meso Ligands To Convey Asymmetry in Enantioselective Catalysis

4. Biaryl Phosphites: New Efficient Adaptative Ligands for Pd-Catalyzed Asymmetric Allylic Substitution Reactions

5. Asymmetric catalysis based on tropos ligands

Cited by 2 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Fluorenyl-tethered N-heterocyclic carbene: An effective ancillary support for heteroleptic magnesium organometallics;Polyhedron;2024-03

2. Fluorenyl-tethered N-heterocyclic carbene (NHC): an exclusive C-donor ligand for heteroleptic calcium and strontium chemistry;Chemical Communications;2024