Structural and thermodynamic similarities of phases in the Li–Tt (Tt = Si, Ge) systems: redetermination of the lithium-rich side of the Li–Ge phase diagram and crystal structures of Li17Si4.0−xGexforx= 2.3, 3.1, 3.5, and 4 as well as Li4.1Ge-Reference-Cited by-同舟云学术

Structural and thermodynamic similarities of phases in the Li–Tt (Tt = Si, Ge) systems: redetermination of the lithium-rich side of the Li–Ge phase diagram and crystal structures of Li17Si4.0−xGexforx= 2.3, 3.1, 3.5, and 4 as well as Li4.1Ge

Published:2014 Issue:40 Volume:43 Page:14959-14970
ISSN:1477-9226
Container-title:Dalton Trans.
language:en
Short-container-title:Dalton Trans.

Author:

Zeilinger Michael¹²³,Fässler Thomas F.¹²³

Affiliation:

1. Department Chemie

2. Technische Universität München

3. 85747 Garching b. München, Germany

Abstract

Li₁₇Ge₄was established as the lithium-richest and Li_4.10Ge as a high-temperature phase in the revised Li-rich section of the Li–Ge phase diagram (>79 at% Li).

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/DT/C4DT00743C

Reference52 articles.

1. Structural Changes in Silicon Anodes during Lithium Insertion/Extraction

2. In Situ XRD and Electrochemical Study of the Reaction of Lithium with Amorphous Silicon

3. A review of the electrochemical performance of alloy anodes for lithium-ion batteries

4. Electrochemically-driven solid-state amorphization in lithium-silicon alloys and implications for lithium storage

5. Electrochemically-driven solid-state amorphization in lithium–metal anodes

Cited by 28 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Applicability of the Zintl Concept to Understanding the Crystal Chemistry of Lithium-Rich Germanides and Stannides;Inorganic Chemistry;2024-05-29

2. Results from Exploratory Work in Li-Rich Regions of the AE-Li-Ge Systems (AE = Ca, Sr, Ba);Crystals;2023-12-31

3. Yet Another Case of Lithium Metal Atoms and Germanium Atoms Sharing Chemistry in the Solid State: Synthesis and Structural Characterization of Ba₂LiGe₃;Chemistry – A European Journal;2023-10-24

4. Self-Organization of Intermetallic Systems: New Cluster-Precursors K12 = 0@12(Li9Ge3) and K9 = 0@9(Li8Ge) Li68Ge16-oC84 in the Crystal Structure, K11 = 0@11(Li6Ge5) and K6 = 0@6(Li5Ge) Cluster-Precursors in the Li44Ge24-oC68 Crystal Structure and K6 = 0@6(Li3Ge3) Cluster-Precursors in the Li12Ge12-tI24 Crystal Structure;Glass Physics and Chemistry;2023-02

5. Influence of the Ge content on the lithiation process of crystalline Si_1−xGe_x nanoparticle-based anodes for Li-ion batteries;Journal of Materials Chemistry A;2023