Influence of the Ge content on the lithiation process of crystalline Si1−xGex nanoparticle-based anodes for Li-ion batteries

Author:

Zapata Dominguez Diana1ORCID,Berhaut Christopher L.2ORCID,Kumar Praveen13,Jouneau Pierre-Henri2,Desrues Antoine4,Herlin-Boime Nathalie4ORCID,Boudet Nathalie5,Blanc Nils5,Chahine Gilbert A.6,Haon Cédric7,Tardif Samuel1ORCID,Lyonnard Sandrine2,Pouget Stéphanie1ORCID

Affiliation:

1. University Grenoble Alpes, CEA, CNRS, IRIG, MEM, F-38000 Grenoble, France

2. University Grenoble Alpes, CEA, CNRS, IRIG, SyMMES, F-38000 Grenoble, France

3. Shared Instrumentation Facility, Colorado School of Mines, Golden, CO, USA

4. University Paris-Saclay, CNRS, CEA, NIMBE, 91191 Gif-sur-Yvette, France

5. University Grenoble Alpes, CNRS, Inst. NEEL, F-38054 Grenoble, France

6. University Grenoble Alpes, CNRS, Grenoble INP, SIMAP, F-38054 Grenoble, France

7. University Grenoble Alpes, CEA, Liten, F-38000 Grenoble, France

Abstract

Crystalline SiGe particles evidence sequential amorphization and the formation of crystalline Li15(Si1−xGex)4 depending on the Ge content upon lithiation.

Funder

Horizon 2020 Framework Programme

Agence Nationale de la Recherche

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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