Syntheses of asymmetrical magnesium(i) complexes and their catalytic application in epoxide hydroboration
Author:
Affiliation:
1. Institute of Material Physics & Chemistry
2. College of Science
3. Nanjing Forestry University
4. Nanjing 210037
5. China
6. College of Pharmacy
7. Nanjing University of Chinese Medicine
8. Nanjing 210023
Abstract
A series of novel structural magnesium(i) complexes stabilized by cyclopentyl and cyclohexyl substituted β-diketiminate ligands have been synthesized and used as highly active and regioselective pre-catalysts for various epoxides hydroboration.
Funder
National Natural Science Foundation of China
Natural Science Foundation of Jiangsu Province
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2020/QO/D0QO00938E
Reference36 articles.
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4. Catalytic Hydroboration of Carbonyl Derivatives, Imines, and Carbon Dioxide
5. Current Developments in the Catalyzed Hydroboration Reaction
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