Vanadium-catalysed regioselective hydroboration of epoxides for synthesis of secondary alcohols-Reference-Cited by-同舟云学术

Vanadium-catalysed regioselective hydroboration of epoxides for synthesis of secondary alcohols

Published:2023 Issue:33 Volume:52 Page:11395-11400
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Zhang Guoqi¹^ORCID,Zeng Haisu¹²,Tang Quan¹,Ates Selin¹,Zheng Shengping²^ORCID,Neary Michelle C.²^ORCID

Affiliation:

1. Department of Sciences, John Jay College and PhD Program in Chemistry, The Graduate Center, The City University of New York, New York, NY 10019, USA

2. Department of Chemistry, Hunter College, the City University of New York, New York, 10065 NY, USA

Abstract

A facile epoxide ring-opening hydroboration reaction catalysed by an active vanadium complex supported by a redox-active terpyridine ligand is reported for the synthesis of secondary alcohols under mild conditions.

Funder

City University of New York

National Science Foundation

American Chemical Society Petroleum Research Fund

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/DT/D3DT01865B

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4. A General Regioselective Synthesis of Alcohols by Cobalt‐Catalyzed Hydrogenation of Epoxides

5. Iron-catalysed regioselective hydrogenation of terminal epoxides to alcohols under mild conditions