Europium-151 and iron-57 nuclear resonant vibrational spectroscopy of naturally abundant KEu(iii)Fe(ii)(CN)6 and Eu(iii)Fe(iii)(CN)6 complexes

Author:

Wang Hongxin1ORCID,Huang Songping D.2ORCID,Yan Lifen1ORCID,Hu Michael Y.3ORCID,Zhao Jiyong3ORCID,Alp Ercan E.3,Yoda Yoshitaka4ORCID,Petersen Courtney M.5,Thompson Matthew K.5ORCID

Affiliation:

1. SETI Institute, Mountain View, CA 94043, USA

2. Department of Chemistry and Biochemistry, Kent State University, Kent, OH 44242, USA

3. Advanced Photon Source, Argonne National Laboratory, Argonne, IL 60439, USA

4. Precision Spectroscopy Division, SPring-8/JASRI, Sayo, Hyogo 679-5198, Japan

5. Department of Chemistry and Biochemistry, The University of Alabama, Tuscaloosa, AL 35487, USA

Abstract

We have performed and analyzed the first combined 151Eu and 57Fe nuclear resonant vibrational spectroscopy (NRVS) for naturally abundant KEu(iii)[Fe(ii)(CN)6] or Eu(iii)[Fe(iii)(CN)6] complex.

Funder

National Institutes of Health

U.S. Department of Energy

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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