Trapping intermediate MLCT states in low-symmetry {Ru(bpy)} complexes-Reference-Cited by-同舟云学术

Trapping intermediate MLCT states in low-symmetry {Ru(bpy)} complexes

Published:2017 Issue:11 Volume:8 Page:7434-7442
ISSN:2041-6520
Container-title:Chem. Sci.
language:en
Short-container-title:Chem. Sci.

Author:

Cadranel Alejandro¹²³⁴⁵^ORCID,Oviedo Paola S.⁶⁷⁸⁹¹⁰,Pieslinger German E.⁶⁷⁸⁹¹⁰^ORCID,Yamazaki Shiori¹¹¹²¹³¹⁴^ORCID,Kleiman Valeria D.¹¹¹²¹³¹⁴^ORCID,Baraldo Luis M.⁶⁷⁸⁹¹⁰^ORCID,Guldi Dirk M.¹²³⁴⁵^ORCID

Affiliation:

1. Department of Chemistry and Pharmacy

2. Interdisciplinary Center for Molecular Materials (ICMM)

3. Friedrich-Alexander-Universität Erlangen-Nürnberg

4. 91058 Erlangen

5. Germany

6. Departamento de Química Analítica

7. Inorgánica y Química Física

8. INQUIMAE

9. Facultad de Ciencias Exactas y Naturales

10. Universidad de Buenos Aires

11. Department of Chemistry

12. University of Florida

13. Gainesville

14. USA

Abstract

The picosecond excited state dynamics of [Ru(tpm)(bpy)(NCS)]⁺ (RubNCS+) and [Ru(tpm)(bpy)(CN)]⁺ (RubCN+) (tpm = tris(1-pyrazolyl)methane, bpy = 2,2′-bipyridine) reveal an intermediate MLCT excited state living in the 300 ps timescale.

Funder

Deutsche Forschungsgemeinschaft

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/SC/C7SC02670F

Reference77 articles.

1. Excited State Tuning of Bis(tridentate) Ruthenium(II) Polypyridine Chromophores by Push-Pull Effects and Bite Angle Optimization: A Comprehensive Experimental and Theoretical Study

2. Controlling Ground and Excited State Properties through Ligand Changes in Ruthenium Polypyridyl Complexes