Unusually high energy barriers for internal conversion in a {Ru(bpy)} chromophore-Reference-Cited by-同舟云学术

Unusually high energy barriers for internal conversion in a {Ru(bpy)} chromophore

Published:2022 Issue:43 Volume:24 Page:26428-26437
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Cotic Agustina¹²^ORCID,Veys Koen³^ORCID,Escudero Daniel³^ORCID,Cadranel Alejandro¹²⁴⁵^ORCID

Affiliation:

1. Universidad de Buenos Aires, Facultad de Ciencias Exactas y Naturales, Departamento de Química Inorgánica, Analítica y Química Física, Ciudad Universitaria, Pabellón 2, C1428EHA, Buenos Aires, Argentina

2. CONICET – Universidad de Buenos Aires, Instituto de Química-Física de Materiales, Medio Ambiente y Energía (INQUIMAE), Ciudad Universitaria, Pabellón 2, C1428EHA, Buenos Aires, Argentina

3. Department of Chemistry, KU Leuven, 3001 Leuven, Belgium

4. Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU), Physical Chemistry I, Egerlandstr. 3, 91058, Erlangen, Germany

5. Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU), Interdisciplinary Center for Molecular Materials, Egerlandstr. 3, 91058, Erlangen, Germany

Abstract

An unusually slow internal conversion (IC) process was demonstrated in a simple charge-transfer chromophore. Insights into the origin of the IC barrier are provided, which could be useful to prevent dissipation in solar energy conversion schemes.

Funder

Fonds Wetenschappelijk Onderzoek

Fondo para la Investigación Científica y Tecnológica

Consejo Nacional de Investigaciones Científicas y Técnicas

KU Leuven

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CP/D2CP03160D

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