Origin of the ligand effect in the cobalt catalyzed regioselective hydroboration of 1,3-diene-Reference-Cited by-同舟云学术

Origin of the ligand effect in the cobalt catalyzed regioselective hydroboration of 1,3-diene

Published:2020 Issue:19 Volume:18 Page:3747-3753
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Liu Yuhua¹²³⁴^ORCID,Jiang ZhongJie⁵⁶⁷⁸⁹^ORCID,Chen Jipei¹²³⁴^ORCID

Affiliation:

1. School of Physics and Electronic Engineering

2. Guangzhou University

3. Guangzhou

4. China

5. Guangzhou Key Laboratory for Surface Chemistry of Energy Materials

6. New Energy Research Institute

7. College of Environment and Energy

8. South China University of Technology

9. Guangzhou 510006

Abstract

The detailed mechanism and the origin of the ligand-controlled regioselectivity in the cobalt catalyzed hydroboration of 2-substituted 1,3-diene have been investigated.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Guangdong Province

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/OB/D0OB00628A

Reference37 articles.

1. P. Ananikov and M.Tanaka , Hydrofunctionalization , Springer , 2013 , vol. 43

2. Hydroboration of alkynes and nitriles using an α-diimine cobalt hydride catalyst

3. Earth-abundant transition metal catalysts for alkene hydrosilylation and hydroboration

4. Cobalt-Catalyzed Hydroboration and Borylation of Alkenes and Alkynes

5. New convenient approach to the preparation of (Z)-allylic boronates via catalytic 1,4-hydroboration of 1,3-dienes with catecholborane

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