Affiliation:
1. State Key Laboratory of Organometallic Chemistry, Center for Excellence in Molecular Synthesis, Shanghai Institute of Organic Chemistry, University of Chinese Academy of Sciences, Chinese Academy of Sciences
Abstract
Incorporation of the boryl moiety across a carbon–carbon multiple bond is a powerful method for the synthesis of organoboron compounds. This kind of transformation could be realized with high chemo-, regio-, and stereoselectivity by using an appropriate transition-metal catalyst. This account summarizes the latest advances from our group in the area of cobalt-catalyzed hydroboration and borylation of alkenes and alkynes, which lead to the formation of a variety of organoboron compounds, including alkylboronates, 1,1,1-tris(boronates), 1,1-diborylalkenes, and 1,1-diboronates.1 Introduction2 Cobalt-Catalyzed Hydroboration of Alkenes3 Cobalt-Catalyzed Dehydrogenative Borylations-Hydroboration4 Cobalt-Catalyzed Double Dehydrogenative Borylations of
1-Alkenes5 Cobalt-Catalyzed Hydroboration of Terminal Alkynes6 Summary and Outlook
Funder
National Natural Science Foundation of China
Cited by
59 articles.
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