A2BiI5O15 (A = K+ or Rb+): two new promising nonlinear optical materials containing [I3O9]3− bridging anionic groups-Reference-Cited by-同舟云学术

A2BiI5O15 (A = K+ or Rb+): two new promising nonlinear optical materials containing [I3O9]3− bridging anionic groups

Published:2014 Issue:20 Volume:2 Page:4057-4062
ISSN:2050-7526
Container-title:J. Mater. Chem. C
language:en
Short-container-title:J. Mater. Chem. C

Author:

Huang Yin¹²³,Meng Xianggao⁴⁵⁶,Gong Pifu⁷⁸⁹¹⁰,Yang Lei⁷⁸⁹¹⁰,Lin Zheshuai⁷⁸⁹¹⁰,Chen Xingguo¹²³,Qin Jingui¹²³

Affiliation:

1. Department of Chemistry

2. Wuhan University

3. Wuhan 430072, China

4. College of Chemistry

5. Central China Normal University

6. Wuhan 430079, China

7. Beijing Center for Crystal R&D

8. Technical Institute of Physics and Chemistry

9. Chinese Academy of Sciences

10. Beijing 100190, China

Abstract

K₂BiI₅O₁₅ and Rb₂BiI₅O₁₅ are synthesized and contain a unique [I₃O₉]³⁻ bridging anionic group. Their powders show phase-matchable SHG effects 3 times that of KDP and the laser damage thresholds of 84 and 72 MW cm⁻², plus wide transparent range and good thermal stability.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/TC/C4TC00264D

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