Mechanism and kinetics of the reaction of the Criegee intermediate CH<sub>2</sub>OO with acetic acid studied using a step-scan Fourier-transform IR spectrometer-Reference-Cited by-同舟云学术

Mechanism and kinetics of the reaction of the Criegee intermediate CH₂OO with acetic acid studied using a step-scan Fourier-transform IR spectrometer

Published:2022 Issue:31 Volume:24 Page:18568-18581
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Behera Bedabyas¹^ORCID,Takahashi Kaito²^ORCID,Lee Yuan-Pern¹³^ORCID

Affiliation:

1. Department of Applied Chemistry and Institute of Molecular Science, National Yang Ming Chiao Tung University, 1001, Ta-Hsueh Road, Hsinchu 300093, Taiwan

2. Institute of Atomic and Molecular Science, Academia Sinica, Taipei 106319, Taiwan

3. Center for Emergent Functional Matter Science, National Yang Ming Chiao Tung University, Hsinchu 300093, Taiwan

Abstract

We observed IR absorption of an open-form and an intramolecularly H-bonded isomer of CH3C(O)OCH2OOH (HPMA). The former was dehydrated to CH3C(O)OC(O)H (FAA) and the latter is stable. Rate coefficients of CH2OO + CH3C(O)OH and HPMA → FAA were derived.

Funder

Ministry of Science and Technology, Taiwan

Academia Sinica

Ministry of Education

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CP/D2CP01053D

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1. Die Ozonisierung des 9,10-Oktalins