Increasing the nuclearity and spin ground state in a new family of ferromagnetically-coupled {Ni10} disk-like complexes bearing exclusively end-on bridging azido ligands-Reference-Cited by-同舟云学术

Increasing the nuclearity and spin ground state in a new family of ferromagnetically-coupled {Ni10} disk-like complexes bearing exclusively end-on bridging azido ligands

Published:2018 Issue:88 Volume:54 Page:12499-12502
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Krause Jasmin¹²³⁴,Alexandropoulos Dimitris I.⁵⁶⁷,Carrella Luca M.¹²³⁴,Rentschler Eva¹²³⁴,Stamatatos Theocharis C.¹²³⁴⁵^ORCID

Affiliation:

1. Institute of Inorganic and Analytical Chemistry

2. Johannes Gutenberg University Mainz

3. D-55128 Mainz

4. Germany

5. Department of Chemistry

6. Ontario

7. Canada

Abstract

A new family of ferromagnetically-coupled {Ni₁₀} complexes was unveiled from the exclusive use of azido bridging ligands; the extended disk-like complexes are stabilized by the presence of various bulky [Ln(NO₃)₅]²⁻ counterions (Ln = lanthanide).

Funder

Natural Sciences and Engineering Research Council of Canada

Alexander von Humboldt-Stiftung

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2018/CC/C8CC07722C

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