In situ generation of Ph3PO in cyanido-bridged heterometallic {FeIIILnIII}2 molecular squares (Ln = Eu, Sm)

Author:

Alexandru Maria-Gabriela12345ORCID,Visinescu Diana678910ORCID,Braun-Cula Beatrice11121314,Shova Sergiu1581610ORCID,Lloret Francesc17181920ORCID,Julve Miguel17181920ORCID

Affiliation:

1. Department of Inorganic Chemistry

2. Physical Chemistry and Electrochemistry

3. Faculty of Applied Chemistry and Materials Science

4. University Politehnica of Bucharest

5. 011061 Bucharest

6. Coordination and Supramolecular Chemistry Laboratory

7. “Ilie Murgulescu” Institute of Physical Chemistry

8. Romanian Academy

9. Bucharest 060021

10. Romania

11. Department of Chemistry

12. Humboldt-Universität zu Berlin

13. 12489 Berlin

14. Germany

15. “Petru Poni” Institute of Macromolecular Chemistry

16. RO-700487 Iasi

17. Departament de Química Inorgànica/Instituto de Ciencia Molecular

18. Universitat de València

19. 46980 Paterna

20. Spain

Abstract

Two new examples of cyanido-bridged {FeIII2(Eu/Sm)III2} molecular squares that exhibit weak antiferromagnetic interactions between 3d and 4f centers are reported.

Funder

Consiliul National al Cercetarii Stiintifice

Unitatea Executiva pentru Finantarea Invatamantului Superior, a Cercetarii, Dezvoltarii si Inovarii

Ministerio de Economía y Competitividad

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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