Comparison of mononuclear and dinuclear copper(<scp>ii</scp>) biomimetic complexes: spectroelectrochemical mechanistic study of their catalytic pathways-Reference-Cited by-同舟云学术

Comparison of mononuclear and dinuclear copper(ii) biomimetic complexes: spectroelectrochemical mechanistic study of their catalytic pathways

Published:2022 Issue:36 Volume:51 Page:13703-13715
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Sýs Milan¹,Kocábová Jana²,Klikarová Jitka¹,Novák Miroslav³^ORCID,Jirásko Robert¹,Obluková Michaela²,Mikysek Tomáš¹,Sokolová Romana²^ORCID

Affiliation:

1. Department of Analytical Chemistry, Faculty of Chemical Technology, University of Pardubice, Studentská 573, 532 10 Pardubice, Czech Republic

2. J. Heyrovský Institute of Physical Chemistry of the CAS, Dolejškova 3, 182 23 Prague 8, Czech Republic

3. Institute of Chemistry and Technology of Macromolecular Materials, Faculty of Chemical Technology, University of Pardubice, Studentská 573, 53210, Pardubice, Czech Republic

Abstract

The catecholase-like biomimetic catalysts were proved for their catechol oxidation catalytic activity in the presence of oxygen and the catalytic mechanism was proposed using voltammetry, in situ UV-Vis spectroelectrochemistry and calculations.

Funder

Grantová Agentura České Republiky

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/DT/D2DT01610A

Reference37 articles.

1. Biomimetic Sensor for Certain Phenols Employing a Copper(II) Complex

2. Structural and Reactivity Models for Copper Oxygenases: Cooperative Effects and Novel Reactivities

3. Ratiometric Electrochemiluminescent Immunoassay for Tumor Marker Regulated by Mesocrystals and Biomimetic Catalyst

4. Real-time sensing of neurotransmitters by functionalized nanopores embedded in a single live cell

5. Monooxygenation of an appended phenol in a model system of tyrosinase: implications on the enzymatic reaction mechanism

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1. Catecholase Activity Assessment of In-Situ Copper Complexes Derived from a Novel Schiff Base Ligand;2023-10-16

2. Spectroelectrochemical study on catecholase catalytic activity of selected mononuclear copper(II) complexes;Electrochimica Acta;2023-09

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4. Unprecedented pseudo-zeroth-order kinetics of the catecholase-like activity of mixed-valence Mn^IIMn₂^III complexes;New Journal of Chemistry;2023