C–C bond migration in the cycloisomerization of 1,6-enynes-Reference-Cited by-同舟云学术

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C–C bond migration in the cycloisomerization of 1,6-enynes

Published:2016 Issue:10 Volume:3 Page:1228-1235
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Stevenson Susan M.¹²³⁴,Newcomb Eric T.⁵⁶⁴,Ferreira Eric M.¹²³⁴

Affiliation:

1. Department of Chemistry

2. University of Georgia

3. Athens

4. USA

5. Arcus Biosciences

6. Hayward

Abstract

Platinum- and iridium-catalyzed cycloisomerizations of 1,6 enynes that proceed via a C–C bond migration into a carbenoid intermediate are described.

Funder

National Institute of General Medical Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/QO/C6QO00224B

Reference71 articles.

1. Transition Metal Catalyzed Cycloisomerizations

2. The Mechanistic Puzzle of Transition-Metal-Catalyzed Skeletal Rearrangements of Enynes

3. Gold and Platinum Catalysis of Enyne Cycloisomerization

4. Catalytic Carbophilic Activation: Catalysis by Platinum and Gold π Acids

5. Relativistic effects in homogeneous gold catalysis

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2. Gold-Catalyzed Cascade Cycloisomerization of 3-Allyloxy-1,6-diynes to Cyclopropyl- and Cyclobutyl-Fused Benzofurans and Chromen-3a(1H)-ols;Organic Letters;2024-03-25

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4. Silver(I)-Catalyzed Oxidative Cyclopropanation of 1,6-Enynes: Synthesis of 3-Aza-bicyclo[3.1.0]hexane Derivatives;Organic Letters;2022-12-09

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