Selectivity control of Pd(PMe3)4-catalyzed hydrogenation of internal alkynes to E-alkenes by reaction time and water content in formic acid-Reference-Cited by-同舟云学术

Selectivity control of Pd(PMe3)4-catalyzed hydrogenation of internal alkynes to E-alkenes by reaction time and water content in formic acid

Published:2019 Issue:27 Volume:48 Page:10033-10042
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Wang Wenmin¹²³⁴⁵,Gao Liuzhou¹²³⁴,Wei Haiyan⁶⁷⁸⁹¹⁰^ORCID,Qi Zheng-Hang¹²³⁴⁵,Zeng Guixiang¹¹²³¹²¹³,Cheng Xu⁵¹⁴²³¹²^ORCID,Wang Guoqiang¹²³⁴,Ma Jing¹²³⁴⁵^ORCID

Affiliation:

1. Key Laboratory of Mesoscopic Chemistry of MOE School of Chemistry & Chemical Engineering

2. Nanjing University

3. Nanjing

4. People's Republic of China

5. Jiangsu Key Laboratory of Advanced Organic Materials

6. Jiangsu Collaborative Innovation Center of Biomedical Functional Materials

7. Jiangsu Provincial Key Laboratory for NSLSCS

8. Jiangsu Key Laboratory of Biomedical Materials

9. School of Chemistry and Materials Science

10. Nanjing Normal University

11. Kuang Yaming Honors School

12. P. R. China

13. Institute for Brain Sciences

14. School of Chemistry and Chemical Engineering

Abstract

The modulation of selectivity of transfer hydrogenation of alkynes to E-alkenes using formic acid is achieved through the control of water content and reaction time.

Funder

National Basic Research Program of China

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/DT/C9DT01676G

Reference76 articles.

1. Modern Trends in Catalyst and Process Design for Alkyne Hydrogenations

2. Hydrogenation of carbon–carbon multiple bonds: chemo-, regio- and stereo-selectivity