Palladium-catalyzed Si–C bond-forming silylation of aryl iodides with hydrosilanes: an enhanced enantioselective synthesis of silicon-stereogenic silanes by desymmetrization

Author:

Chen Li1234,Huang Jiang-Bo1234,Xu Zheng1234,Zheng Zhan-Jiang1234,Yang Ke-Fang1234,Cui Yu-Ming1234,Cao Jian1234,Xu Li-Wen12345

Affiliation:

1. Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education

2. Hangzhou Normal University

3. Hangzhou 311121

4. P. R. China

5. State Key Laboratory for Oxo Synthesis and Selective Oxidation

Abstract

An enantioselective Pd-catalyzed silicon–carbon bond-forming silylation reaction of aryl iodides with hydrosilanes for the synthesis of silicon-stereogenic silanes has been developed with good enantioselectivity under mild conditions.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Reference69 articles.

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2. Electrophilic Substitution of Organosilicon Compounds- Applications to Organic Synthesis

3. M. A. Brook , Silicon in Organic, Organometallic, and Polymer Chemistry , Wiley-Interscience , New York , 1999

4. Solid-Phase, Pd-Catalyzed Silicon-Aryl Carbon Bond Formation. Synthesis of Sansalvamide A Peptide

5. Palladium-Catalyzed Silylation of Aryl Bromides Leading to Functionalized Aryldimethylsilanols

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