Catalytic reactivity of an iridium complex with a proton responsive N-donor ligand in CO2 hydrogenation to formate-Reference-Cited by-同舟云学术

Catalytic reactivity of an iridium complex with a proton responsive N-donor ligand in CO2 hydrogenation to formate

Published:2018 Issue:3 Volume:8 Page:1346-1350
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Gunasekar Gunniya Hariyanandam¹²³⁴^ORCID,Yoon Yeahsel¹²³⁴,Baek Il-hyun⁵⁶⁴^ORCID,Yoon Sungho¹²³⁴^ORCID

Affiliation:

1. Department of Applied Chemistry

2. Kookmin University

3. Seoul

4. Republic of Korea

5. Korea Institute of Energy Research

6. Daejeon 305-343

Abstract

A bibenzimidazole ligated half-sandwich Ir complex [Cp*Ir(BiBzImH₂)Cl]Cl shows superior activity than that of its bipyridine counterpart. Owing to the structural instability, the initial excellent activity of [Cp*Ir(BiBzImH₂)Cl]Cl was reduced when catalytic cycle proceeds.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/RA/C7RA12343D

Reference34 articles.

1. Recent advances in the homogeneous hydrogenation of carbon dioxide

2. Homogeneous Catalysis in Supercritical Fluids: Hydrogenation of Supercritical Carbon Dioxide to Formic Acid, Alkyl Formates, and Formamides

3. An effective heterogeneous Ir(III) catalyst, immobilized on a heptazine-based organic framework, for the hydrogenation of CO2 to formate

4. Interconversion of CO2 and formic acid by bio-inspired Ir complexes with pendent bases

5. A Covalent Triazine Framework, Functionalized with Ir/N-Heterocyclic Carbene Sites, for the Efficient Hydrogenation of CO2 to Formate

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