Affiliation:
1. School of Chemistry and Chemical Engineering Nanjing University 210093 Nanjing P. R. China
Abstract
AbstractThere is widespread interest in the hydrogenation of CO2 to produce high‐energy substances such as formic acid. Herein, ruthenium trichloride was immobilized on porous phosphine polymers (Ru/KAPs‐Ph‐PPh3) and gave excellent catalytic activity in the hydrogenation of CO2 to produce formate. With the assistance of 1,8‐diazabicyclo[5.4.0]undec‐7‐ene (DBU), a high turnover number (TON) of up to 1470000 was obtained in 12 hours at 120 °C and a total pressure of 6 MPa (P(H2)/P(CO2)=1 : 1), with average TOFs of 122500 h−1. Moreover, the catalyst can be easily recovered by filtration with acceptable catalytic effectiveness.
Funder
National Natural Science Foundation of China
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Catalysis
Cited by
1 articles.
订阅此论文施引文献
订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献