Anharmonic IR spectra of solvated ammonium and aminium ions: resemblance between water and bisulfate solvations

Author:

Lin Chih-Kai1ORCID,Kuo Jer-Lai234ORCID

Affiliation:

1. Department of Chemistry, National Taiwan University, Taipei, 10617, Taiwan, Republic of China

2. Institute of Atomic and Molecular Sciences, Academia Sinica, Taipei, 10617, Taiwan, Republic of China

3. Department of Chemistry, National Tsing Hua University, Hsinchu 30013, Taiwan, Republic of China

4. International Graduate Program of Molecular Science and Technology, National Taiwan University, Taipei, 10617, Taiwan, Republic of China

Abstract

Ammonium/aminium cations solvated by either water molecules or bisulfate anions show resemblance in their vibrational spectra, indicating a common anharmonic coupling mechanism.

Funder

Ministry of Science and Technology, Taiwan

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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