Generation and direct EPR spectroscopic observation of triplet arylphosphinidenes: stabilisation versus internal rearrangements-Reference-Cited by-同舟云学术

Generation and direct EPR spectroscopic observation of triplet arylphosphinidenes: stabilisation versus internal rearrangements

Published:2020 Issue:47 Volume:22 Page:27626-27631
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Misochko Eugenii Ya.¹²³^ORCID,Akimov Alexander V.¹²³,Korchagin Denis V.¹²³^ORCID,Ganushevich Yulia S.⁴⁵³^ORCID,Melnikov Egor A.⁴⁵³,Miluykov Vasili A.⁴⁵³

Affiliation:

1. Institute of Problems of Chemical Physics of RAS

2. Chernogolovka

3. Russia

4. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center, Russian Academy of Sciences

5. Kazan

Abstract

Phosphinidene – to be or not to be: only the arylphosphinidenes with relatively small ortho-substituents are kinetically stable. EPR spectra of such stabilized intermediates have been detected for the first time.

Funder

Russian Foundation for Basic Research

Ministry of Education and Science of the Russian Federation

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2020/CP/D0CP05254J

Reference23 articles.

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5. Coordination‐Like Chemistry of Phosphinidenes by Phosphanes

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