Free Ethynylarsinidene and Ethynylstibinidene: Heavier Analogues of Nitrenes and Phosphinidenes

Abstract

AbstractUntil now, there has been very little experimental evidence for the existence of free arsinidenes and stibinidenes, apart from the hydrides, AsH and SbH. Here, we report on photogeneration of triplet ethynylarsinidene, HCCAs, and triplet ethynylstibinidene, HCCSb, from ethynylarsine and ethynylstibine, respectively, in solid argon matrices. The products were identified using infrared spectroscopy and the associated UV absorption spectra are interpreted with the aid of theoretical predictions.