In situ investigation of the formation mechanism of α-Bi2Rh nanoparticles in polyol reductions-Reference-Cited by-同舟云学术

In situ investigation of the formation mechanism of α-Bi₂Rh nanoparticles in polyol reductions

Published:2022 Issue:45 Volume:51 Page:17405-17415
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Smuda Matthias¹,Ströh Jonas²,Pienack Nicole²,Khadiev Azat³,Terraschke Huayna²^ORCID,Ruck Michael¹⁴^ORCID,Doert Thomas¹^ORCID

Affiliation:

1. Faculty of Chemistry and Food Chemistry, Technische Universität Dresden, 01062 Dresden, Germany

2. Institute of Inorganic Chemistry, Christian-Albrechts-Universität zu Kiel, Max-Eyth-Str. 2, 24118 Kiel, Germany

3. Deutsches Elektronen-Synchrotron DESY, Notkestr. 85, 22607 Hamburg, Germany

4. Max Planck Institute for Chemical Physics of Solids, öthnizer Str 40, 01187 Dresden, Germany

Abstract

The study of Bi2Rh formation in a polyol process revealed a two-step mechanism. BiRh is formed by co-reduction of bismuth and rhodium cations and converted into Bi2Rh by Bi diffusion. Various starting materials and reaction parameters are examined.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/DT/D2DT02273G

Reference42 articles.

1. Intermetallics in catalysis: An exciting subset of multimetallic catalysts

2. Intermetallic compounds in catalysis – a versatile class of materials meets interesting challenges

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4. Many More Superconducting Bismuth Phases

5. Kristallstruktur und zwillingsbildung der intermetallischen phase β-Bi2Rh

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