Activation of group 15 based cage compounds by [CpBIGFe(CO)2] radicals-Reference-Cited by-同舟云学术

Activation of group 15 based cage compounds by [CpBIGFe(CO)2] radicals

Published:2014 Issue:8 Volume:5 Page:3221-3225
ISSN:2041-6520
Container-title:Chem. Sci.
language:en
Short-container-title:Chem. Sci.

Author:

Heinl Sebastian¹²,Scheer Manfred¹²

Affiliation:

1. University of Regensburg

2. 93040 Regensburg, Germany

Abstract

The sterically encumbered complex [Cp^BIGFe(CO)₂]₂ (1) (Cp^BIG = pentakis(4-n-butylphenyl)cyclopentadienyl) forms in solution radicals, which enable the selective cleavage of a E–E single bond (E = P, As) in the cage molecules P₄, As₄, P₄S₃ and P₄Se₃, respectively, already at room temperature.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/SC/C4SC01213E

Reference34 articles.

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