Resolving the backbone tilt of crystalline poly(3-hexylthiophene) with resonant tender X-ray diffraction-Reference-Cited by-同舟云学术

Resolving the backbone tilt of crystalline poly(3-hexylthiophene) with resonant tender X-ray diffraction

Published:2022 Issue:6 Volume:9 Page:1649-1657
ISSN:2051-6347
Container-title:Materials Horizons
language:en
Short-container-title:Mater. Horiz.

Author:

Freychet Guillaume¹^ORCID,Chantler Paul²,Huang Yuxuan³,Tan Wen Liang²,Zhernenkov Mikhail¹^ORCID,Nayak Nagaraj⁴,Kumar Anil⁴^ORCID,Gilhooly-Finn Peter A.⁵⁶,Nielsen Christian B.⁵^ORCID,Thomsen Lars⁷,Roychoudhury Subhayan⁸,Sirringhaus Henning³^ORCID,Prendergast David⁸^ORCID,McNeill Christopher R.²^ORCID

Affiliation:

1. NSLS-II, Brookhaven National Laboratory, Upton, NY 11973, USA

2. Department of Materials Science and Engineering, Monash University, Wellington Road, Clayton, Victoria, 3800, Australia

3. Cavendish Laboratory, University of Cambridge, JJ Thomson Avenue, Cambridge, CB3 0HE, UK

4. Department of Chemistry, Indian Institute of Technology Bombay, Powai, Mumbai, 400076, India

5. Department of Chemistry, Queen Mary University of London, Mile End Road, London, E1 4NS, UK

6. Department of Chemistry, University College London, 20 Gordon Street, London, WC1H 0AJ, UK

7. Australian Synchrotron, ANSTO, 800 Blackburn Road, Clayton, Victoria, 3168, Australia

8. The Molecular Foundry, Lawrence Berkeley National Laboratory, 1 Cyclotron Road, Berkeley, CA 94720, USA

Abstract

Exploiting the interaction between polarized tender X-rays and the planar conjugated backbone, resonant tender X-ray diffraction is able to resolve the tilting of the backbone within the unit cell.

Funder

U.S. Department of Energy

Engineering and Physical Sciences Research Council

FP7 Ideas: European Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Electrical and Electronic Engineering,Process Chemistry and Technology,Mechanics of Materials,General Materials Science

Link

http://pubs.rsc.org/en/content/articlepdf/2022/MH/D2MH00244B

Reference37 articles.

1. π-Conjugated Polymers for Organic Electronics and Photovoltaic Cell Applications