H2 activation by zirconaziridinium ions: σ-bond metathesis versus frustrated Lewis pair reactivity-Reference-Cited by-同舟云学术

H2 activation by zirconaziridinium ions: σ-bond metathesis versus frustrated Lewis pair reactivity

Published:2020 Issue:17 Volume:56 Page:2542-2545
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Budzelaar Peter H. M.¹²³⁴^ORCID,Hughes David L.⁵⁶⁷⁸^ORCID,Bochmann Manfred⁵⁶⁷⁸^ORCID,Macchioni Alceo¹⁹¹⁰¹¹⁴^ORCID,Rocchigiani Luca⁵⁶⁷⁸^ORCID

Affiliation:

1. Department of Chemistry

2. University of Naples Federico II

3. Naples

4. Italy

5. School of Chemistry

6. University of East Anglia

7. Norwich

8. UK

9. Biology and Biotechnology and CIRCC

10. University of Perugia

11. Perugia

Abstract

Zirconaziridinium salts cleave H₂ by a stepwise mechanism, where initial σ-bond metathesis of the Zr–C bond enables subsequent heterolytic splitting through metal–amine cooperation.

Funder

University of East Anglia

Università degli Studi di Perugia

Ministero dell’Istruzione, dell’Università e della Ricerca

H2020 European Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2020/CC/C9CC09466K

Reference38 articles.

1. Ion pairing effects in intramolecular heterolytic H2 activation in an Ir(iii) complex: a combined theoretical/experimental study

2. Activation of dihydrogen and coordination of molecular H2 on transition metals

3. Frustrated Lewis Pair Chemistry: Development and Perspectives

4. Frustrated Lewis Pairs: From Concept to Catalysis

5. Frustrated Lewis Pairs

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