Incorporation of catechyl monomers into lignins: lignification from the non-phenolic end via Diels–Alder cycloaddition?-Reference-Cited by-同舟云学术

Incorporation of catechyl monomers into lignins: lignification from the non-phenolic end via Diels–Alder cycloaddition?

Published:2021 Issue:22 Volume:23 Page:8995-9013
ISSN:1463-9262
Container-title:Green Chemistry
language:en
Short-container-title:Green Chem.

Author:

Ando Daisuke¹^ORCID,Lu Fachuang¹²^ORCID,Kim Hoon¹^ORCID,Eugene Alexis¹^ORCID,Tobimatsu Yuki³^ORCID,Vanholme Ruben⁴⁵^ORCID,Elder Thomas J.⁶^ORCID,Boerjan Wout⁴⁵^ORCID,Ralph John¹⁷⁸^ORCID

Affiliation:

1. Department of Energy, Great Lakes Bioenergy Research Center, Wisconsin Energy Institute, Madison, Wisconsin 53726, USA

2. State Key Laboratory of Pulp and Paper Engineering, South China University of Technology, 381 Wushan Rd, Tianhe District, Guangzhou, 510640, P.R. China

3. Research Institute for Sustainable Humanosphere, Kyoto University, Gokasho, Uji, 611-0011, Japan

4. Department of Plant Biotechnology and Bioinformatics, Ghent University, B-9052 Gent, Belgium

5. Center for Plant Systems Biology, VIB, B-9052 Gent, Belgium

6. USDA-Forest Service, Southern Research Station, 521 Devall Drive, Auburn, AL 36849, USA

7. Department of Biochemistry, University of Wisconsin-Madison, Madison, Wisconsin 53706, USA

8. Department of Biological System Engineering, University of Wisconsin-Madison, Madison, Wisconsin 53726, USA

Abstract

Catechyl monomers 1-electron-oxidize and undergo radical coupling to produce benzodioxane units in lignin. Derived o-quinones undergo Diels–Alder reactions giving oxatricyclo and new benzodioxane products, but does this occur in lignification?.

Funder

Basic Energy Sciences

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/GC/D1GC03022A

Reference82 articles.

1. K.Freudenberg and A. C.Neish , Constitution and Biosynthesis of Lignin , Springer-Verlag , Berlin-Heidelberg-New York , 1968

2. K. V.Sarkanen and C. H.Ludwig , Lignins: Occurrence, Formation, Structure and Reactions , Wiley-Interscience , New York , 1971