Facilitated electron transfer by Mn dopants in 1-dimensional CdS nanorods for enhanced photocatalytic hydrogen generation

Author:

MacSwain Walker1ORCID,Lin Hanjie1,Li Zhi-Jun1ORCID,Li Shuya1,Chu Chun1,Dube Lacie2,Chen Ou2,Leem Gyu34ORCID,Zheng Weiwei1ORCID

Affiliation:

1. Department of Chemistry, Syracuse University, Syracuse 13244, New York, USA

2. Department of Chemistry, Brown University, Providence, 02912, Rhode Island, USA

3. Department of Chemistry, State University New York College of Environmental Science Forestry, Syracuse 13210, New York, USA

4. The Michael M. Szwarc Polymer Research Institute, 1 Forestry Drive, Syracuse 13210, New York, USA

Abstract

The long lifetime of Mn2+ dopants (∼ms) facilitates charge separation and electron transfer in Mn2+ doped 1D CdS nanorods (NRs) with Pt tips (i.e., Mn:CdS-Pt NRs), which significantly enhances photocatalytic water splitting for hydrogen generation.

Funder

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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