How does the solvent composition influence the transport properties of electrolyte solutions? LiPF6 and LiFSA in EC and DMC binary solvent
Author:
Affiliation:
1. Research Institute of Electrochemical Energy
2. National Institute of Advanced Industrial Science and Technology (AIST)
3. Ikeda
4. Japan
Abstract
Competitive Li+-solvation between EC and DMC and the hydrodynamic size of transporting entities are quantitatively examined as a function of the solvent composition from the experimentally determined data.
Funder
Japan Society for the Promotion of Science
Publisher
Royal Society of Chemistry (RSC)
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy
Link
http://pubs.rsc.org/en/content/articlepdf/2021/CP/D1CP00967B
Reference48 articles.
1. Nonaqueous Liquid Electrolytes for Lithium-Based Rechargeable Batteries
2. Pulse-Gradient Spin-Echo 1H, 7Li, and 19F NMR Diffusion and Ionic Conductivity Measurements of 14 Organic Electrolytes Containing LiN(SO2CF3)2
3. An Evaluation Method of Liquid Electrolytes for Lithium Batteries by the Multinuclear Pulsed-gradient Spin-echo NMR—The Diffusing Radii of Lithium Ion and Anions in Organic Solvents
4. Temperature Dependence of Self-Diffusion Coefficients of Ions and Solvents in Ethylene Carbonate, Propylene Carbonate, and Diethyl Carbonate Single Solutions and Ethylene Carbonate + Diethyl Carbonate Binary Solutions of LiPF6 Studied by NMR
5. Investigation of solvation in lithium ion battery electrolytes by NMR spectroscopy
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