Phase-controlled synthesis of Ni nanocrystals with high catalytic activity in 4-nitrophenol reduction

Author:

Zhuang Jiahao12345,Liu Xianglin61784,Ji Yongjun5910114ORCID,Gu Fangna5910114ORCID,Xu Jing61784,Han Yi-fan61784,Xu Guangwen1213144,Zhong Ziyi151617418ORCID,Su Fabing5910114ORCID

Affiliation:

1. School of Chemical Engineering

2. University of Chinese Academy of Sciences

3. Beijing 100049

4. China

5. State Key Laboratory of Multiphase Complex Systems

6. State Key Laboratory of Chemical Engineering

7. East China University of Science and Technology

8. Shanghai 200237

9. Institute of Process Engineering

10. Chinese Academy of Sciences

11. Beijing 100190

12. Institute of Industrial Chemistry and Energy Technology

13. School of Chemical Engineering Shenyang University of Chemical Technology

14. Shenyang

15. College of Engineering

16. Guangdong Technion Israel Institute of Technology (GTIIT)

17. Shantou

18. Technion Israel Institute of Technology, (IIT)

Abstract

The phase-controlled synthesis and formation mechanism of Ni nanocrystals with hcp and fcc phases are investigated and discussed, while hcp Ni shows comparable catalytic activity with the best noble metal catalysts for reduction of 4-nitrophenol.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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