Affiliation:
1. Department of Materials Science and Engineering Research Institute of Advanced Materials and Institute of Engineering Research Seoul National University Gwanak‐ro 1, Gwanak‐gu Seoul 08826 Republic of Korea
2. Institute for Materials Research Tohoku University Kitahira 2‐1‐1 Sendai 980‐8577 Japan
Abstract
AbstractThe liquid metal dealloying (LMD) process enables the fabrication of porous metals with various chemical compositions. Despite its advantages, LMD still faces key challenges such as maintaining the high‐temperature molten metal bath for a prolonged time, avoiding the use of toxic etchants, and so on. To overcome these challenges, the study develops a water‐leachable and oxidation‐resistant alloy melt (AM) in Ca‐Mg binary system. Specifically, Ca72Mg28 eutectic AM is designed, which exhibits higher oxidation resistance and lower melting temperature compared to pure Mg, allowing LMD to be conducted in atmospheric conditions as well as temperatures >200 K lower. The AM also enables an innovative process to fabricate Ti foams with a hexagonal faceted surface structure by carefully manipulating the etching rate during the water etching process. This approach allows for the creation of foam with a surface area over 13% larger than that of foams with smooth surfaces via normal acid etching, potentially enhancing efficiency in applications such as electrodes for electrochemical systems or biomedical materials where increased cell adhesion can be beneficial. This study paves the way for efficiently manipulating the LMD process to fabricate metal foams with customized compositions and enhanced surface properties.
Funder
Ministry of Science and ICT, South Korea