Asymmetric transfer hydrogenation of imines in water/methanol co-solvent system and mechanistic investigation by DFT study-Reference-Cited by-同舟云学术

Asymmetric transfer hydrogenation of imines in water/methanol co-solvent system and mechanistic investigation by DFT study

Published:2014 Issue:86 Volume:4 Page:46351-46356
ISSN:2046-2069
Container-title:RSC Adv.
language:en
Short-container-title:RSC Adv.

Author:

Shende Vaishali S.¹²³,Shingote Savita K.¹²³,Deshpande Sudhindra H.¹²³,Kuriakose Nishamol⁴²³,Vanka Kumar⁴²³,Kelkar Ashutosh A.¹²³

Affiliation:

1. Chemical Engineering and Process Development

2. National Chemical Laboratory

3. Pune 411008, India

4. Physical and Materials Chemistry Division

Abstract

Asymmetric transfer hydrogenation of various cyclic imines proceeded efficiently with H₂O/MeOH (1 : 1, v/v) co-solvent media in 20 min with excellent yields and enantioselectivities by using Rh–TsDPEN catalyst and HCOONa as a hydrogen donor.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/RA/C4RA07964G

Reference40 articles.

1. Catalytic Enantioselective Addition to Imines

2. Enantioselective Hydrogenation of Imines Using a Diverse Library of Ruthenium Dichloride(diphosphine)(diamine) Precatalysts

3. Asymmetric Transfer Hydrogenation of Imines

4. A Chiral Rhodium Complex for Rapid Asymmetric Transfer Hydrogenation of Imines with High Enantioselectivity

5. A One-Pot Process for the Enantioselective Synthesis of Amines via Reductive Amination under Transfer Hydrogenation Conditions

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