Catalyst-free transfer hydrogenation of activated alkenes exploiting isopropanol as the sole and traceless reductant

Author:

Das Tamal Kanti1ORCID,Rodriguez Treviño Agustin M.1ORCID,Pandiri Sanjay1,Irvankoski Sini2ORCID,Siitonen Juha H.2,Rodriguez Sara M.3,Yousufuddin Muhammed3,Kürti László1ORCID

Affiliation:

1. Department of Chemistry, Rice University, Houston, Texas 77030, USA

2. Department of Chemistry and Materials Science, Aalto University, FI-02150 Espoo, Finland

3. Department of Natural Sciences, University of North Texas at Dallas, Dallas, Texas 75241, USA

Abstract

Described herein is an unconventional catalyst-free transfer hydrogenation reaction of activated alkenes using isopropanol as an eco-friendly reductant and solvent.

Funder

Consejo Nacional de Ciencia y Tecnología

Welch Foundation

National Science Foundation

National Institutes of Health

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

Reference102 articles.

1. J. G.de Vries and C. J.Elsevier , The Handbook of Homo-geneous Hydrogenation , Wiley-VCH , Weinheim , 2007

2. P. G.Andersson and I. J.Munslow , Modern Reduction Methods , Wiley-VCH Verlag GmbH & Co. KGaA , Weinheim , 2008

3. D.San-Filippo and P. N.Rylander , Hydrogenation and Dehydrogenation. In Ullmann's Encyclopedia of Industrial Chemistry , Wiley-VCH Verlag GmbH & Co. KGaA , 2009

4. The Golden Age of Transfer Hydrogenation

5. Ueber das Verhalten des Δ 2.5 ‐Dihydroterephtalsäuredimethylesters bei höheren Temperaturen und in Gegenwart von Palladiummohr

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