A case study on the conversion of Li/Cl phosphinidenoid into phosphinidene complexes-Reference-Cited by-同舟云学术

A case study on the conversion of Li/Cl phosphinidenoid into phosphinidene complexes

Published:2021 Issue:2 Volume:50 Page:739-745
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Junker Philip¹²³⁴,Qu Zheng-Wang⁵⁶⁷⁴^ORCID,Kalisch Tim¹²³⁴,Schnakenburg Gregor¹²³⁴,Espinosa Ferao Arturo⁸⁹¹⁰¹¹^ORCID,Streubel Rainer¹²³⁴^ORCID

Affiliation:

1. Institut für Anorganische Chemie

2. Rheinische Friedrich-Wilhelms-Universität Bonn

3. 53121 Bonn

4. Germany

5. Mulliken Center for Theoretical Chemistry

6. Rheinischen Friedrich-Wilhelms-Universität Bonn

7. 53115 Bonn

8. Departamento de Química Orgánica. Facultad de Química. Universidad de Murcia

9. Campus de Espinardo

10. 30100 Murcia

11. Spain

Abstract

Transient, thermally very labile Li/Cl phospinidenoid W(CO)₅ complexes were generated to yield E–H insertion products in THF while Umpolung occurred in toluene that was shown by trapping with terminal alkenes.

Funder

Deutsche Forschungsgemeinschaft

Rheinische Friedrich-Wilhelms-Universität Bonn

Universidad de Murcia

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/DT/D0DT03884A

Reference86 articles.

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3. A stable crystalline carbene

4. Analogous .alpha.,.alpha.'-bis-carbenoid, triply bonded species: synthesis of a stable .lambda.3-phosphino carbene-.lambda.5-phosphaacetylene

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