Solvent-mediated precipitating synthesis and optical properties of polyhydrido Cu<sub>13</sub> nanoclusters with four vertex-sharing tetrahedrons-Reference-Cited by-同舟云学术

Solvent-mediated precipitating synthesis and optical properties of polyhydrido Cu₁₃ nanoclusters with four vertex-sharing tetrahedrons

Published:2023 Issue:4 Volume:14 Page:994-1002
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Lin Xinzhang¹²^ORCID,Tang Jie¹²,Zhu Chenyu¹,Wang Li³,Yang Yang¹²,Wu Ren'an³^ORCID,Fan Hongjun⁴^ORCID,Liu Chao¹^ORCID,Huang Jiahui¹^ORCID

Affiliation:

1. Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China

2. University of Chinese Academy of Sciences, Beijing 100049, China

3. Laboratory of High-Resolution Mass Spectrometry Technologies, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China

4. State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China

Abstract

A solvent-mediated precipitating synthesis was developed to efficiently prepare novel high-purity Cu13H10(SR)3(PPh3)7 nanoclusters with an aesthetic crystal structure, unique optical properties and ultrafast relaxation dynamics.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/SC/D2SC06099J

Reference73 articles.

1. [Cu36H10(PET)24(PPh3)6Cl2] Reveals Surface Vacancy Defects in Ligand-Stabilized Metal Nanoclusters

2. [Pt2Cu34(PET)22Cl4]2–: An Atomically Precise, 10-Electron PtCu Bimetal Nanocluster with a Direct Pt–Pt Bond

3. Core-dependent properties of copper nanoclusters: valence-pure nanoclusters as NIR TADF emitters and mixed-valence ones as semiconductors