Core-dependent properties of copper nanoclusters: valence-pure nanoclusters as NIR TADF emitters and mixed-valence ones as semiconductors-Reference-Cited by-同舟云学术

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Core-dependent properties of copper nanoclusters: valence-pure nanoclusters as NIR TADF emitters and mixed-valence ones as semiconductors

Published:2019 Issue:43 Volume:10 Page:10122-10128
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Zhang Leon Li-Min¹²³,Zhou Guodong⁴²³^ORCID,Zhou Guoqing⁵⁶⁷⁸,Lee Hung-Kay¹²³,Zhao Ni⁴²³^ORCID,Prezhdo Oleg V.⁵⁶⁷⁸^ORCID,Mak Thomas C. W.¹²³^ORCID

Affiliation:

1. Department of Chemistry and Center of Novel Functional Molecules

2. The Chinese University of Hong Kong

3. People's Republic of China

4. Department of Electronic Engineering

5. Department of Chemistry

6. University of Southern California

7. Los Angeles

8. USA

Abstract

While valence-pure copper alkynyl nanoclusters show near-infrared TADF, the mixed-valence ones exhibit semiconductivity.

Funder

Wei Lun Foundation

Chinese University of Hong Kong

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/SC/C9SC03455B

Reference87 articles.

1. Alkynyl Approach toward the Protection of Metal Nanoclusters

2. Polyhydrido Copper Clusters: Synthetic Advances, Structural Diversity, and Nanocluster-to-Nanoparticle Conversion

3. Discovery, Mechanism, and Application of Antigalvanic Reaction

4. Role of Anions Associated with the Formation and Properties of Silver Clusters

5. A Mono-cuboctahedral Series of Gold Nanoclusters: Photoluminescence Origin, Large Enhancement, Wide Tunability, and Structure–Property Correlation

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